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It is shown that the unit cell volumedoes not vary significantly below 80 K. This anomalous behavior, correlated with the existence of aweak ferromagnetic ordering revealed from superconducting quantum interference device experiments,is similar to that characteristic of Invar alloys. Just above the Curie temperature T ~ 73 ± 5 K, theCr AlC undergoes significant distortions of the octahedron and triangular prisms units. 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